Creation, Categorization and Application of Metal Organic Framework of Zirconium Benzene-1,4-Dicarboxylic Acid in Adsorption of Crude Oil
Keywords:
Zirconium benzene-1,4-dicarboxylic, Adsorption, MOF, Crude oil
Abstract
Zr-BDA was made by reacting benzene-1,4-dicarboxylic acid with zirconium chloride (ZrCl4) using the solvothermal technique. The structure of the synthesized MOF was examined using energy dispersive X-ray spectroscopy (EDX), scanning electron microscopy (SEM), and Fourier transform infrared spectroscopy (FTIR). It was discovered that the resulting MOF had a high degree of crystallinity and surface area. The Zr-MOF's FTIR spectrum showed the presence of many functional groups as well as the potential development of a brand-new group. Comparing the new functional group to the pure spectrum of benzene-1,4-dicarboxylic acid reveals the creation of the MOF. Functional groups such as C-H, C-O, O-H, C=C, and metal-oxygen were noted. Adsorption tests revealed Zr-BDA has a 70% efficiency, which is neither appropriate nor advised. However, composites with charcoal and pH enhanced Zr-BDA's adsorptive capabilities for the crude oil.
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Furukawa, H., Cordova, K. E., O'Keeffe, M., & Yaghi, O. M. (2013). The chemistry and applications of metal-organic frameworks. Science, 341(6149), 1230444.
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Hessel, V. & Löwe, H. (2003). Microchemical Engineering: Components, Plant Concepts User Acceptance – Part I. Chemical Engineering & Technology, 26(1), 13-24.
Hoskins, B. F. & Robson, R. (1990). Design and construction of a new class of scaffolding-like materials comprising infinite polymeric frameworks of 3D-linked molecular rods. A reappraisal of the zinc cyanide and cadmium cyanide structures and the synthesis and structure of the diamond-related frameworks [N(CH3)4][CuIZnII(CN)4] and CuI[4,4',4'',4''' tetracyanotetraphenylmethane] BF4.xC6H5NO2. Journal of the American Chemical Society, 112(4), 1546-1554.
Leuan, T. H., Laybourn, A., Dodds, C., & Kingman, S. W. (2018). Realising the environmental of metal-organic frameworks: recent advances in microwave synthesis. Journal of Materials Chemistry, 6(25), 11564-11581.
Li, G., Kobayashi, H., Taylor, J. M., Ikeda, R., Kubota, Y., Kato, K., ... & Kitagawa, H. (2014). Hydrogen storage in Pd nanocrystals covered with a metal–organic framework. Nature Materials, 13(8), 802-806.
Li, H., Eddaoudi, M., O'Keeffe, M., & Yaghi, O. M. (1999). Design and synthesis of an exceptionally stable and highly porous metal-organic framework. Nature, 402(6759), 276-279.
Lide, D. R. (2007). Zirconium. In Lide, D. R. (Ed.), Handbook of Chemistry and Physics (4th ed., pp. 42). New York: CRC Press.
Ma, S. (2009). Gas adsorption applications of porous metal–organic frameworks. Pure and Applied Chemistry, 81(12).
Mircea, D., & Long, J. R. (2008). Hydrogen storage in microporous metal-organic frameworks with exposed metal sites. Angewandte Chemie International Edtion, 47(36), 6766-6779.
Musza, K., Szabados, M., Adam, A. A., Belteky, P., Kónya, Z., Kukovecz, A., ... & Pálinkó, I. (2021). Mechanochemical synthesis of the NiSn, CuSn bimetallic and NiCuSn trimetallic nanocomposites using various types of additives. Journal of Solid State Chemistry, 293, 121756.
Orodu, V. E., & Dikio, E. D. (2021). Synthesis, Characterization and Adsorption Study of Metal Organic Framework of Copper (II) benzene-1, 4-dicarboxylate (Cu-MOF) on Crude oil. Progress in Materials Chemistry and Physics, 2(1), 1-14.
Pachfule, P., Das, R., Poddar, P., & Banerjee, R. (2011). Solvothermal Synthesis, Structure, and Properties of Metal Organic Framework Isomers Derived from a Partially Fluorinated Link. Crystal Growth & Design, 11(4), 1215-1222.
Ryder, M. R., & Tan, J. C. (2014). Nanoporous metal organic framework materials for smart applications. Materials Science and Technology, 30(13), 1598-1612.
Sikora, B. J., Wilmer, C. E., Greenfield, M. L., & Snurr, R. Q. (2012). Thermodynamic analysis of Xe/Kr selectivity in over 137000 hypothetical metal–organic frameworks. Chemical Science, 3(7), 2217-2223.
Stock, N. & Biswas, S. (2012). Synthesis of metal-organic frameworks (MOFs): routes to various MOF topologies, morphologies, and composites. Chemical Reviews, 112(2), 93369.
Wang, B., Cote, A. P., Furukawa, H., O'Keeffe, M., & Yaghi, O. M. (2008). Colossal cages in zeolitic imidazolate frameworks as selective carbon dioxide reservoirs. Nature, 453(7192), 207-11.
Yaghi, O. M. (2007). Metal-organic Frameworks: A tale of two entanglements. Nature Materials, 6(2), 92-93.
Yaghi, O. M., O'Keeffe, M., Ockwig, N. W., Chae, H. K., Eddaoudi, M., & Kim, J. (2003). Reticular synthesis and the design of new materials. Nature, 423(6941), 705-714.
Zhang, L., Liand, F., & Luo, L. (2018). Preparation methods of metal organic frameworks and their capture of CO2. In IOP Conference Series: Earth and Environmental Science (Vol. 108, No. 4, p. 042104). IOP Publishing.
Zhou, H. C., Long, J. R., & Yaghi, O. M. (2012). Introduction to metal–organic frameworks. Chemical Reviews, 112(2), 673-674.
Published
2024-07-08
How to Cite
Orodu, V. E., Dakitima, E. P., & Dikio, E. D. (2024). Creation, Categorization and Application of Metal Organic Framework of Zirconium Benzene-1,4-Dicarboxylic Acid in Adsorption of Crude Oil. European Journal of Science, Innovation and Technology, 4(3), 343-353. Retrieved from https://ejsit-journal.com/index.php/ejsit/article/view/463
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Copyright (c) 2024 Victor Enearepuadoh Orodu, Egioni Philip Dakitima, Ezekiel Dixon Dikio
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